OK, I see what you’re getting at.
Resistant starch has been shown to be effective for a hypoglycemia-inducing condition called glycogen storage disease.
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3808112/
The hypoglycemia caused by GSD is similar in ways to bonking. The rationale for how resistant starch works is that it’s digestion-resistant nature leads to slower production and absorption of monosaccharides through digestion. Thus resistant starches would have lower glycemic indices than comparable starches.
This sounds like it might be a good candidate for race-day fuel, but an important caveat is that resistant starches are also “feeding” your enteric bacteria, which may increase intestinal gas and cause cramping. So like anything else you might do on a race day, you should test it out ahead of time.
Getting back to your original question, the fact that starches can be processed to increase their resistant content means that it’s not a given that UCAN is equivalent to ordinary starch from the same plant. If you do try UCAN vs ordinary starch, I would cook then cool the starch first to increase the resistant content.
The paper that I linked says that conventional Argo cornstarch is 60% resistant whereas the modified starch that they used in the study is 67% resistant (Table 1), so the difference is small enough that you might achieve this by cooking it at home. They also cite this study as the source of their protocol for making resistant starch:
https://www.ncbi.nlm.nih.gov/m/pubmed/17514432/