This is one of those evergreen topics.
Calling Daniels a "charlatan" is absurd. He's one of the giants of exercise science, and he's also a real coach who has worked with many of the best American runners of the last 50+ years. I do think that some of his advice is outdated, though.
As xel noted, Daniels hasn't historically considered paces slower than LT2 to be meaningful workout paces. He throws marathon pace in there for marathoners, but he thinks it's largely a psychological workout. Modern training, on the other hand, places a huge amount of emphasis on paces from LT1 to LT2. Double thresholds are run at those intensities, for instance. It's worth noting that this isn't entirely a new phenomenon; it's trendy now, but most athletes doing "tempo runs" in the 70s and 80s were going slower than LT2. It's largely because of Daniels that people came to think of tempo pace as maximum lactate steady state.
I think another reason that slower tempos have come into vogue is because the influence of Canova made marathon specific training so much more popular. Elites and high level amateurs started doing tons of MP mileage while training for marathons, and they realized that they were also getting incredibly strong aerobically, in a way that carried over to shorter distances as well.
The other huge difference between Daniels and modern training is the emphasis on avoiding "grey zones" between target paces. According to Daniels, we run at specific paces to stimulate specific adaptations, and paces between those will give you less bang for your buck. For instance, 10k pace would be a no-man's land between VO2max pace and LT1, so not a useful training stimulus. Athletes today hit all the paces. It can be particularly useful in the context of year-round training, where you want to maintain what you've built even if it's not your primary training emphasis. So if you're in a specific phase for the marathon, for instance, you can run "B" workouts that alternate between 3k, 5k, and 10k pace. It will maintain that high end aerobic capacity that you worked on earlier, but it takes less out of you than just doing straight 3k work.
And yet, even though I disagree with a lot of Daniels, I think he gets a ton right.
If you look at the training of modern athletes, a lot of it still fits the Daniels mold pretty well. While we might be a little less rigid about the zones, VO2max pace and LT2 pace are still mainstays (the latter more commonly as intervals than as straight tempos these days). His periodization also holds up pretty well. And his use of R pace for true distance runners is also pretty modern. (It was always in his books, but even a lot of Daniels-influenced coaches didn't do much of that faster running 20-30 years ago, whereas now, distance runners do a lot more work at faster paces.)
Daniels was also hugely important for the resurgence of American distance running because the book was widely available, and it's well suited to coaching high school and college runners. In the 90s and early 00s, there was far less information out there about coaching. It's one of the reasons this website got so huge. People were desperate for this stuff. Daniels provided an easy to apply formula to train an entire team. The pace tables were invaluable. (Seriously, it's hard to imagine now, but a lot of coaches used to just say that workouts should be about as hard as possible. e.g., if we were doing 12x400 w/ 1 minute rest. we should run them even, but at the fastest possible average pace.)
The specific paces he emphasized were also fairly race-specific for cross country runners, so even though there's nothing magic about VO2max pace, it ends up getting you into good race shape. It also worked well for middle distance runners at the time because the guys they were competing against all overemphasized anaerobic training.
Finally, I think if you're going to criticize Daniels, you should be careful to read what he actually wrote, especially in later editions of his book. If you summarize his philosophy in a nutshell and look at his plans, it seems pretty rigid, but if you really get into the text of the book, you'll see a lot more flexibility and nuance. One key point that a lot of people miss is that the formula paces are supposed to be based on your most recent performance, not your PR or your goal. Some of the workouts or weeks that look like monsters aren't actually that scary if you're being honest about your paces. (Years ago, I was presenting a training schedule at a coaching course--probably my Level 2--and I recall an instructor saying, "well, if your plan was to focus on VO2max, these intervals should be at 3k pace, not at 5k pace like you specified." I said, "when's the last time you told your athletes to run 5k pace and they didn't actually run 3k pace?" Daniels assumes you're being totally honest about paces, which is totally fair for a book. It's up to the coach to figure out how to implement it, either by giving slower target paces or by being super rigid about athletes following instructions.)