For the doubling options, I have always thought that as long as each run is more than 20 minutes, it doesn't particularly matter how they are split up (in terms of fitness). Assuming a world without life responsibilities (ha!), I would go with #2 - I just like getting in the "main" run in the morning with a "shakeout" in the PM.
#4 is distinctly different because all the running gets done at once - more aerobic fitness benefits that splitting the 90 minutes between two runs, but probably incurring a bit more fatigue.
To me, the real answer is to sometimes do whichever of options 1-3 works best for you when you want the economy benefits of 90 minutes of running with less fatigue and quicker recovery, and other times to option 4 when you want to maximize aerobic benefits. They serve slightly different purposes, so incorporate both as appropriate to your training needs.