I usually end up closer to 85 before doubling while training for marathon.
Looking back at my 3 full marathon cycles, I hit 75 miles or more 16 times.
I doubled 5 of those weeks, with the mileage totals for the weeks that I doubled being 76 (first ever marathon cycle, near my highest ever mileage week) 80, 90, 91, 100. of those 12 weeks that were at or above 75 but in which I did not double, most were 80 or above. I never hit 90 or above without doubling.
I think the two schools of thought on doubling during marathon training are:
1. It is better to run some doubles because they beat your body up a little less and they result in HGH and other hormones being released in greater quantities since those hormones tend to be released for the first 30 minutes of exercise then level off (so you get two releases when you double compared to a single release when you run singles).
2. Getting in as many double digit/70 minute or longer singles as possible has the benefit of touching on your various glycogen stores (muscle stores, liver stores) and working through those stores more often may result in greater efficiency in switching between those stores over time. (Plus, there is the mental aspect of having a 10 or 11 miler seem like a normal day, which makes the 26 mile seem just a hint less intimidating).