Asking for the difference between doing 3 doubles/week versus 4 doubles is one of those questions you aren't going to get a clear answer on. There are a few benefits/negatives to look at, but I feel that either way you do it, it won't make a large difference on performance at the end of the summer.
Some things to note about 3 versus 4 doubles:
Doing 4 doubles is mentally tougher becuase that's 1 more day you have to get up early to run twice. However, it allows you a little more rest between miles. You can run in shorter spurts because you are doing it in 4 sessions versus 3. This is slightly less stress on your body. Think about the difference between cruise intervals and a straight through tempo run. The difference is that cruise intervals allow you to run slightly longer/farther than 1 straight tempo because the run is broken up and allows your body a slight break from the stress. I realize you want to stay at 24 miles no matter what but it still breaks it up for you and reduces the stress level, somewhat.
*On a sidenote, it's not always about the quantity (miles), but rather, about the quality (time) spent on your runs. There should always be a purpose - you should never go running just to add another 2.5 miles to your total so you have exactly 100 for the week. There should always be a REASON and goal for your run (recovery, aerobic, anaerobic, speed, LT, strength, etc). This is why I suggest switching it up depending on how your body feels that week. If you are feeling tired and beat up, do 4 doubles of 6 miles each to split it up, or just do 3 doubles of 6 miles each and don't force yourself to do the extra 4 simply to have "x" miles for the week. Garbage mileage isn't beneficial in the end if it hurts your performance. If you are feeling strong, keep a good recovery pace but maybe do the 3 doubles of 8 miles each for a little more of an aerobic effort.