If we just include outdoor (road/track) running (not walking or field) events from 100m to marathon length that are official World Athletics World Record events, you want what the 5K times of the following athletes would be when they set their world record in their respective event (i.e: not what their actual current 5K PB is unless they are the 5K WR holder):
M:
Bolt (100m/200m)
Merritt (110m hurdles)
van Niekerk (400m)
Warholm (400m hurdles)
Rudisha (800m)
Ngeny (1000m)
El G (1500m/Mile)
Giles (Mile Road)
Ingebrigtsen (2000m/3000m)
Girma (3000m Steeplechase)
Chep (5000m/10000m) - we already know his time, 12:35.36.
Aregawi (5K Road/10K Road) - we also know his time, 12:49 on the roads which is certainly faster on the track.
Farah (One Hour Run)
Kejelcha (Half Marathon)
Kiptum (Marathon)
W:
Flo-Jo (100m/200m)
Amusan (100m hurdles)
Koch (400m)
SML (400m hurdles)
Kratochvílová (800m)
Masterkova (1000m)
Kipyegon (1500m/Mile)
Welteji (Mile Road)
Hull (2000m)
Junxia (3000m)
Chepkoech (3000m Steeplechase)
Tsegay (5000m) - we already know her time, 14:00.21.
Chebet (5K Road Wo, 10000m) - 14:13 on the roads, faster on track.
Ngetich (5K Road Mx en route to 10K Road Mx) - 14:13 split. If she split this in a 10K then she could certainly go faster in a road 5K or track 5000m.
Tirop (10K Road Wo)
Hassan (One Hour)
Gidey (Half Marathon Mx)
Jepchirchir (Half Marathon Wo/Marathon Wo)
Chepngetich (Marathon Mx)
You can technically get the fastest en-route split of any athlete whose race was longer than a 5K and that could be their "time", but I know you are referring to what their 5K time would be if they applied their WR fitness level in whatever their primary event was to the 5K only.