It's one run you're missing; the risk isn't worth the reward.
As others have said, running a double on a long run day isn't necessarily a bad thing.
However, when you're not running a lot of mileage (I'm assuming), adding an additional 8kms in the afternoon - after what is quite possibly your most physiologically taxing run of the week - is a little bit silly.
The old adage "don't try to make up for lost training" applies here. Your week is scheduled the way it is, so that it allows intermittent recovery. Clustering lots of runs together without gradually building that into your training can easily put you over the edge.
If your regular long run is 14 miles, maybe just do 15 miles this week instead, and leave it at that.