I doubt that any NFL player could do it without doing distance training for several months. It would be like asking an elite miler to run sub-11 for 100m. I'm certain that many of them have the talent to do it if they devoted a block of training solely to weights and sprint work but few if any could do it while running close to 100 mpw.
One player who might have a chance at becoming a middle distance stud if he were to ever focus on it is Brandon Banks, who briefly had a stint in the NFL before coming to the CFL as a wide receiver/returner. He's listed as 5"7 and 153 lbs but his trainer says that he weighs 140.
He ran 10.4 and 21.4 seconds for the 100m and 200m in high school and is nearly untouchable as a kick returner. In the East Division final last year, he returned 2 punts for touchdowns (plus another that was called back) and returned another for a touchdown in the final minute of the championship game, that likely would have won his team the title had it not also been called back on an illegal block.
He's likely good enough to be a strong returner in the NFL but probably won't be given a chance as he's too small to also play receiver and the NFL usually reserves special teams-only positions for players fresh out of college so that they can be payed less.
Another guy in the CFL who I've heard has run 1:5X for 800m is receiver Rob Bagg.