Can be a useful training tool, as most things can be, but don't kill your athletes.
Running first thing in the morning when you're low on liver glycogen is one thing, but that "starve" word raises some red flags. I've experimented with back to back long(er) runs on Saturday and Sunday, in order to limit some of that glycogen recovery in between the two. For example, a hard-ish effort for 13 miles on Saturday and then an easy 15-16 miler on Sunday. You would probably increase mileage for both of those for marathon training, as I am certainly not a marathoner.
I also know some coaches who would have runners do a weekly ten mile morning run with another ten mile afternoon-evening run, to increase the quality/speed of mileage over just 20 straight.
I can tell you, pretty much straight up, that restricting carbohydrates isn't going to limit glycogen stores if you're still going calorie heavy in the other two macro-nutrients. Gluconeogenesis is a thing, and your body is going to use whatever you give it to fuel your legs. I would personally, for that reason, lean towards more mileage with split runs in order to run pre-fatigued, but I'm always willing to listen to other peoples experiments!