Squigley-
Wearing a general superfeet orthotic will not necessarily prevent you from pronating. Unless you have a flatter arch that collapses pretty far, then the rigid orthotic will hold it up.
If you are dealing with PF I recommend getting a pair of superfeet insoles. The rigidity along the arch will help lessen the stress on your PF.
In terms of structure vs pegasus, the 2 other posters are right. Go get checked by someone that appears half way competent at a local running store. Being in support when you don't need it can be just as bad as being a neutral shoe when you need support.